Various types of energy and environmental devices have been demonstrated. The rapid growth of deformable and stretchable electronics calls for a deformable and stretchable power source. Highly conductive nise 2 nanostructures for allsolidstate. Paper efficient synthesis of tungsten oxide hydratebased nanocomposites for applications in bifunctional electrochromicenergy storage devices to cite this article.
Paper, invented more than 2,000 years ago and widely used today in our everyday lives, is explored in this study as a platform for energy storage devices by integration with 1d nanomaterials. Pdf paper, invented more than 2000 years ago and widely used today in our everyday. Recently, bendable and rollable electronic devices e. Dec 22, 2009 in addition, this conductive paper can be used as an excellent lightweight current collector in lithiumion batteries to replace the existing metallic counterparts. Custommade electrochemical energy storage devices acs.
Paper supercapacitors by a solventfree drawing method. A variety of near, mid, and longterm storage options can simultaneously provide multiple benefits that have the. Nanoscale design of zinc anodes for highenergy aqueous. A selfhealable and highly stretchable supercapacitor. Previous breakthroughs in stretchable electronics stem from strain engineering and nanocomposite approaches.
Multidimensional materials and device architectures for. Oct 11, 2018 metal oxide based electrodes are attractive for energy storage applications with limited characteristics of flexibility due to inherent rigid structure. While ultracapacitors are able to deliver high rates of charge and discharge, they are limited in the amount of energy stored. Psscnf porous nanocomposite papers showed a lower sulfur content, indicating the removal of residual pss.
Pdf highly conductive paper for energystorage devices. The design of highly selfhealable and stretchable devices is a radical element in the development of many unprecedented applications such as. Here, we show that commercially available paper can be made highly conductive with a sheet resistance as low as 1 ohm per square. With the rapid development of portable and flexible electronic devices, there is an evergrowing demand for lightweight, flexible, and stretchable energy storage devices, such as solar cells, lithium batteries,, and supercapacitors. Highly conductive paper for energystorage devices europe pmc.
This work has demonstrated that the pyramidlike nise 2 nanostructure is expected to be an ideal high specific capacity electrode for bsh devices, especially for allsolidstate energy storage devices and portable electronic devices. Researchers at stanford university seem to have done it again. Based electrodes for flexible energy storage devices. Use of graphene in flexible energy storage devices. Dec 22, 2015 the design of highly selfhealable and stretchable devices is a radical element in the development of many unprecedented applications such as electronic skin 1,2 and smart energy storage clothes 3,4. Origami lithiumion batteries zeming song1, teng ma1, rui tang2, qian cheng1, xu wang1, deepakshyam krishnaraju1, rahul panat1, candace k. Flexible, highly graphitized carbon aerogels based on. This time, a paper titled highly conductive paper for energy storage devices, published on the proceedings of the national academy of sciences, describes a. Highly conductive paper for energy storage devices. Ultraflexible and robust graphene supercapacitors printed on. Paperlike electrodes with high conductivity and flexibility hold great potential for assembling highperformance flexible electronic devices.
Electrodeposition of silver ag nanoparticles on mno 2. A thin layer of metal is first deposited to make paper substrate more electrically conductive. More importantly, this work provides a good reference for the fabrication of other types of hybrid paper electrodes. Metal oxide based electrodes are attractive for energy storage applications with limited characteristics of flexibility due to inherent rigid structure. Ultracapacitors are rapidly being adopted for use for a wide range of electrical energy storage applications. Advanced materials and devices for stationary electrical energy. May 29, 2015 even though recent advances have been made with interdigitated twodimensional 2d devices or semi3d devices 2,3,4,5, only a few examples of full 3d energy storage devices have been shown 6,7,8.
Recent progress on printable power supply devices and. Study on ion conductive materials for novel energy storageconversion devices department of materials molecular science division of molecular functions chemical energy conversionstorage using electrochemical devices such as fuel cells and batteries will become increasingly important for future sustainable societies. It can be bent and twisted, trimmed with scissors or molded into any needed shape. Moreover, with the continued miniaturization of electronics, integration of wireless devices into our homes and clothes and the widely anticipated internet of things, there are intensive efforts to develop miniature yet powerful electrical energy storage devices. We present a novel method to prepare highly conductive, freestanding, and flexible porous carbon thin films by chemical activation of reduced graphene oxide paper. Electrochemical testing determined that birnessite nanotubecontaining fibres presented the most viable option for energy storage device applications. As a result, the development of highly conductive omc electrodes with excellent mechanical properties is desirable in the field of flexible energy storage devices. Using the birnessite nanotubecontaining fibre, fibrebased supercapacitors were fabricated and investigated. The proposed device is lifree and uses zinc and silver. Flexible holey graphene paper electrodes with enhanced. A highly stretchable and washable allyarnbased self.
This work suggests that our conductive paper can be a highly scalable and lowcost solution. These power devices are highly promising for allintegrated paper and textile electronics. Highly conductive freestanding graphene films as anode current. This is in fact the predicted behavior for a highly conductive electrode when all surface area is. Paperbased energy storage devices ian robertson literature seminar november 7, 20 paper has been used as the substrate of choice for information storage and transmission for over 2000 years in the form of writing. Connecting two hybrid devices in series is able to drive a red led for more than 3 min after charging for 9 s. The side with cnts a and without cnts b of the conductive paper soaked in organic electrolyte 1 m lipf 6 in ecdec. Aug 27, 2018 connecting two hybrid devices in series is able to drive a red led for more than 3 min after charging for 9 s.
The nano materials are a onedimensional structure with very small diameters. Highly conductive and porous activated reduced graphene. In conclusion, we have made highly conductive cnt paper by conformal coating of cnts onto commercial paper, whose conductivity can be further enhanced by incorporating metal nanowire strips as global current collectors for largescale energystorage devices figs. The capacity of ultracapacitors is largely determined by the electrode material and as a result, research to improve the performance of electrode materials has. Highly conductive and flexible paper of 1d silvernanowire. Highly conductive paper for energystorage devices article pdf available in proceedings of the national academy of sciences 10651. Related content mno2gc3n4 nanocomposite with highly. Highly conductive freestanding graphene films as anode. Free synthesis and its application in energy storage devices xuezhu xu department of mechanical engineering, north dakota state university, fargo, nd, 58102 usa.
Tests on the stability of paper in the organic electrolyte. Ultraflexible and robust graphene supercapacitors printed. Jan 14, 20 paper battery a paper battery is a flexible, ultrathin energy storage and production device formed by combining carbon nanotubes with a conventional sheet of cellulosebased paper. Flexible and stretchable allsolidstate supercapacitors are of considerable interest as promising energy storage devices for wearable electronics.
Study on ion conductive materials for novel energy storage. Xueting chang et al 2018 nanotechnology 29 185707 view the article online for updates and enhancements. From industrially weavable and knittable highly conductive. Highly conductive, freestanding and flexible graphene papers for energy conversion and storage devices article in rsc advances 322. Wearable electronic textiles that store capacitive energy are a next frontier in personalized electronics. In this study, a flexible conductive film was fabricated via vacuum filtration using highly conductive moo3. The ideal electrode architecture consisting of 3d highly. Highly conductive, freestanding and flexible graphene papers. Paperbased devices for energy applications iowa state university. Highly conductive and flexible molybdenum oxide nanopaper for. Dec 22, 2009 paper, invented more than 2,000 years ago and widely used today in our everyday lives, is explored in this study as a platform for energystorage devices by integration with 1d nanomaterials. The intrinsic properties of paper, such as high solvent absorption and strong binding with nanomaterials, allow easy and scalable coating procedures. Printable fabrication of a fully integrated and self.
The gf network is used as a highly conductive pathway for electrons, ions. A selfhealable and highly stretchable supercapacitor based. This paper demonstrates a family of highly conductive multimaterial composites that can be directly printed into readytouse multifunctional electrical devices using a flexible solventcast 3d printing technique. The ideal electrode architecture consisting of 3d highly conductive scaffold coated with nanosized electroactive. Advanced materials and devices for stationary electrical.
Stationary energy storage technologies promise to address the growing limitations of u. Even though recent advances have been made with interdigitated twodimensional 2d devices or semi3d devices 2,3,4,5, only a few examples of. Stretchable allsolidstate supercapacitors based on. Highly conductive, freestanding and flexible graphene. In addition, this conductive paper can be used as an excellent lightweight current collector in lithiumion batteries to replace the existing metallic counterparts. Recent citations textile sensors for wearable applications. Synthesis of silver nanowires for highly conductive and transparent films. However, a major obstacle to the realization of bendable energy storage devices is the lack of reliable materials that have superior electrical conductivity, high. Highly conductive and flexible molybdenum oxide nanopaper. However, incorporation of flexible insulating matrix within metal oxide composites result in poor electrically conductive and energy storage characteristics. Highly conductive paper for energystorage devices pnas. With conductive liquid contained in a polymer cover, a shapeadaptive triboelectric nanogenerator sateng unit can effectively harvest energy in various. Apr 15, 2015 flexible, highly graphitized carbon aerogels based on bacterial celluloselignin.
The morphology and microstructure of the asprepared three cuco 2 s 4 samples were investigated by fesem, tem, hrtem and saed as displayed in fig. Cvd graphene paper possesses much higher electrical conductivity of 1097 scm, compared. Highly conductive nise 2 nanostructures for allsolid. Here pristine soft conductive yarns are continuously produced by a scalable method with the use of twistbundledrawing. Flexible holey graphene paper electrodes with enhanced rate capability for energy storage applications. Here, we show that commercially available paper can be made highly conductive with a sheet resistance as low as 1 ohm per. Although considerable effort has been devoted to investigate flexible and stretchable supercapacitors, challenges remain in developing supercapacitors with the combination of flexibility, high. These results suggest that the hybrid paper is a promising electrode material and may be useful for the development of flexible highperformance and handheld energy storage devices. Electrical energy storage plays a vital role in daily life due to our dependence on numerous portable electronic devices. Paper battery a paper battery is a flexible, ultrathin energy storage and production device formed by combining carbon nanotubes with a conventional sheet of cellulosebased paper. Flexible, highly graphitized carbon aerogels based on bacterial celluloselignin. In the past decade, there has been a large amount of. Stretchable allsolidstate supercapacitors based on highly. This work suggests that our conductive paper can be a highly scalable and lowcost solution for highperformance energy storage devices.
Synthesis of silver nanowires for highly conductive and transparent films show all authors. Based electrodes for flexible energy storage devices yao. Energy and environmental nanotechnology in conductive paper and. Paperbased energy storage devices chemistry at illinois. Recent progress on printable power supply devices and systems with nanomaterials yuanjing lin1, yuan gao1, fang fang2, and zhiyong fan1 1 department of electronic and computer engineering, the hong kong university of science and technology, hong kong, china 2 department of materials science, fudan university, shanghai 200433, china present address. Paper, invented more than 2,000 years ago and widely used today in our everyday lives, is explored in this study as a platform for energystorage devices by.
A novel architecture of graphene paper is proposed to consist of 1d metallic nanowiresdefect free graphene sheets. Flexible, highly conductive, and freestanding reduced. These flexible carbon thin films possess a very high specific surface area of 2400 m2 g. Highly conductive and flexible papers of 1d silver nanowires ag nws and chemical vapor deposition cvd graphene sheets as an example were fabricated by a simple filtration method. Synthesis of silver nanowires for highly conductive and. There is an everincreasing interest in energy storage devices that not only store energy but which are also flexible, stretchable, or structural. However, the lack of industrially weavable and knittable conductive yarns in conjunction with high capacitance, limits the widescale application of such textiles. A customizable electrochemical energy storage device is a key. Threedimensional 3d printing with conductive polymer nanocomposites provides an attractive strategy for the ondemand fabrication of electrical devices.
Paper based energy storage devices ian robertson literature seminar november 7, 20 paper has been used as the substrate of choice for information storage and transmission for over 2000 years in the form of writing. Efficient synthesis of tungsten oxide hydratebased. Largearea paper batteries with ag and znag screenprinted. Paper efficient synthesis of tungsten oxide hydratebased nanocomposites for applications in bifunctional electrochromic energy storage devices to cite this article. Recent advancements in stretchable electronics have blurred the interfaces between human and machine 1, 2. Highly conductive and porous activated reduced graphene oxide. Such freestanding films with integrated current collectors and electrode. Origami lithiumion batteries washington state university.
As an important class of energy storage devices, flexible and stretchable supercapacitors have attracted intensive research interest. A highly stretchable, transparent, and conductive polymer. To fully realize flexible electronics, integrated flexible energy storage is needed. Freeform and deformable energy storage as a forerunner.
In this paper, we report the fabrication of highly conductive poly3,4ethylenedioxythiophenepolystyrenesulfonate pedot. More recently, we and the other groups produced a promising freestanding 3d graphene foam structure by chemical vapor deposition cvd with nickel foams or al 2 o 3 ceramics as 3d. This study presents the fabrication of flexible mno2 based composite electrodes. Among most of the mechanical energy harvesting systems. Althouse, and nian liu school of chemical and biomolecular engineering, georgia institute of technology, atlanta, georgia 30332, usa correspondence.
Among all flexible energy storage devices, supercapacitors and. We report a scalable approach for energy harvesters and selfpowered sensors that can be highly deformable and stretchable. The nano materials are a onedimensional structure with very. Psscellulose nanofiber cnf nanocomposite paper with excellent flexibility through posttreatment with an organic solvent. Controllable preparation of highly uniform cuco2s4. Fabrication of highly conductive porous cellulosepedot. A novel architecture of graphene paper is proposed to consist of 1d metallic nanowiresdefectfree graphene sheets. Controllable preparation of highly uniform cuco2s4 materials. Highly conductive, free standing and flexible graphene papers for energy conversion and storage devices article in rsc advances 322. However, paper and textile substrates are not electrically conductive for electrons.
372 547 248 1511 175 542 354 1279 1612 1285 1037 1533 1119 499 1029 1198 593 671 1010 714 1285 690 1230 1275 566 825 307 268 730 374 1439